Knowledge · the 17 nutrients

The 17 nutrients a crop needs, and why the one in shortest supply limits the harvest

A crop needs 17 nutrients. It takes 3 of them from air and water and the other 14 from the soil, in amounts that range from tens of kilograms an acre down to grams an acre. Crops use these nutrients in the same way on every farm. A grower who understands how they work can make better fertiliser choices. Each nutrient has its own job in the plant, its own signs of shortage, and other nutrients it works with or against. Liebig’s Law of the Minimum explains why a crop given plenty of urea can still grow poorly: growth is limited by the nutrient in shortest supply.

From air and water

The crop takes carbon, hydrogen and oxygen from air and water. They are not bought as fertiliser, and together they make up more than 90% of the plant’s dry weight.

Major nutrients: the 3 needed in the largest amounts

Most of a grower’s fertiliser spending goes on nitrogen, phosphorus and potassium. Most fertiliser mistakes also involve these 3. The usual mistake is too much of 1 and too little of the other 2.

Secondary nutrients: 3 needed in moderate amounts

A crop takes up calcium, magnesium and sulfur in amounts measured in kilograms an acre, close to the amount of phosphorus it takes up. They are the nutrients most often left out of fertiliser programmes in Pakistan.

Micronutrients: 8 needed in grams

A crop needs each micronutrient only in grams an acre, but it cannot complete its growth if any 1 of them is missing. A crop given plenty of nitrogen can still grow poorly because of a shortage of zinc.

The Law of the Minimum · Justus von Liebig, 1840s

Liebig’s barrel: how the nutrient in shortest supply limits the crop

In the 1840s the German chemist Justus von Liebig set out the Law of the Minimum: a crop’s growth is limited by the nutrient in shortest supply compared with what the crop needs, and adding more of any other nutrient does not raise that limit. The law is usually shown as a wooden barrel in which each stave stands for 1 nutrient. The barrel holds water only up to the top of its shortest stave. If nitrogen is not the shortest stave, another bag of urea makes the nitrogen stave taller, but the water level stays at the top of the shortest stave.

Enter the number of packs or bags of each product you applied to 1 acre this season. Each pack size is shown as printed on the pack.

VAN products

General grades

N36 kgP₂O₅20 kgK₂O12 kgS4.8 kgZn0.68 kgB0.22 kgMg0.55 kgFe0.02 kgMn0.02 kgCu0.01 kgEach stave is 1 nutrient. Full height is the amount in VAN’s wheat crop plan per acre

Enter what you applied and the staves fill. The dotted outline of each stave shows the crop plan’s amount, and the label under it gives that amount in kilograms an acre.

Each stave shows the amount of 1 nutrient you applied as a share of the amount in VAN’s published crop plan for that crop, per acre. The shortest stave is the nutrient with the smallest share.

The 11 nutrients a grower manages

What each nutrient does, what a shortage looks like, and which nutrients it works with

N

Nitrogen

Major nutrients: the 3 needed in the largest amounts

Nitrogen is part of every protein and of chlorophyll. It determines how much leaf the crop grows and how green the leaves are. The leaves make the sugars that fill the grain.

When it is short
Older leaves turn pale yellow first, from the tip back, because the plant moves nitrogen out of old leaves into new ones. Plants stay small and thin. Grain has less protein.
Works with, and against
The plant needs sulfur to turn nitrogen into protein. A crop short of sulfur cannot use all the nitrogen it is given, and the nitrogen it does not use is lost from the field. A crop also needs potassium to make good use of nitrogen: nitrogen drives leaf growth, and potassium moves sugar out of the leaf. Nitrogen without enough potassium gives soft, tall growth that falls over.
In Pakistan’s soils
Pakistan applies more nitrogen than any other nutrient, and a larger share of the nitrogen is lost than of any other nutrient. Its nitrogen use efficiency was 29.1% in 2023 (FAOSTAT): about 71 of every 100 kg of nitrogen added to its cropland were not taken out in the harvested crop. Sulfur coated urea (SCU) releases its nitrogen gradually, over days rather than all at once, so more of it reaches the roots than from uncoated urea.
P

Phosphorus

Major nutrients: the 3 needed in the largest amounts

Inside the plant, phosphorus is used to move energy, and the plant needs it to grow roots. It affects how fast a seedling puts down roots, how many tillers wheat makes, and how well the crop sets and fills its grain.

When it is short
Seedlings grow slowly and are dark green, sometimes with a purple tint on the older leaves and stems. The crop makes fewer tillers, flowers late and forms small heads. Most of the damage is done in the first weeks and cannot be undone later.
Works with, and against
Phosphorus and zinc work against each other: a heavy dose of phosphate on a soil already low in zinc makes the zinc shortage worse. Inside the plant, phosphorus needs calcium. In the soil, calcium binds phosphate into forms the root cannot take up. This binding is the central phosphorus problem in Pakistan’s soils.
In Pakistan’s soils
In the Punjab soil survey (770,160 samples, tested in about 2016 to 2018), the median available phosphorus (measured as elemental phosphorus) was in the Critical or Weak band of VAN’s 5-band soil-test scale in 35 of the 36 districts. In the same survey, 69.1% of samples were above pH 8, and calcareous soil above pH 8 binds applied phosphate before the root reaches it. The Soil Atlas shows each district.
K

Potassium

Major nutrients: the 3 needed in the largest amounts

Potassium controls the movement of water and sugar in the plant. It opens and closes the pores in the leaf, moves sugar from the leaf to the grain, tuber or fruit, and thickens the cell wall. It affects crop quality, grain weight and tolerance of stress: heat, drought and disease all do more damage to a crop that is short of potassium.

When it is short
Older leaves scorch along the edge and the tip while the centre of the leaf stays green. Stems are weak and the crop falls over (lodges). Grain is light, and fruit is small and stores badly.
Works with, and against
Potassium works with nitrogen: nitrogen drives leaf growth, and potassium moves sugar from the leaf to fill the grain. Too much potassium reduces the plant’s uptake of magnesium and calcium. Potassium, magnesium and calcium should therefore be planned together, not each applied on its own.
In Pakistan’s soils
In 2024-25, potash was 1% of the fertiliser nutrients applied in Pakistan (NFDC). VAN prints this figure on its Crop Force bag. VAN’s wheat balance page shows how much potash a wheat crop of 60 maunds per acre removes from the field when the straw (bhoosa) is also taken away.
Ca

Calcium

Secondary nutrients: 3 needed in moderate amounts

Calcium holds the cell walls together and is needed at every growing point. Once calcium is placed in a tissue it does not move again, so the crop needs a steady supply while it grows, especially where fruit and tubers are forming.

When it is short
The youngest tissue fails first: new leaves have burnt tips, tomatoes get blossom end rot, apples get bitter pit and potatoes get hollow heart. Old leaves look normal.
Works with, and against
Calcium and boron work together to build the cell wall, and boron is needed for calcium to move to the growing point. Too much potassium or magnesium in the soil reduces the calcium the root takes up.
In Pakistan’s soils
Pakistan’s soils hold a great deal of calcium in the form of lime. A crop can still be short of calcium, because the calcium in lime is not in a form the root can take up, and because a heavy dose of potash blocks its uptake.
VAN products that contain it
Mg

Magnesium

Secondary nutrients: 3 needed in moderate amounts

Magnesium sits at the centre of every chlorophyll molecule, so without it the leaf cannot stay green or make sugar. It also helps the plant move phosphorus.

When it is short
Older leaves go yellow between the veins while the veins stay green, giving a striped or marbled look. The yellowing starts on the lower leaves and moves up the plant.
Works with, and against
Too much potassium or too much calcium reduces the magnesium a crop takes up. When a fertiliser programme raises the potash dose without adding magnesium, the crop often shows a magnesium shortage in the same season.
S

Sulfur

Secondary nutrients: 3 needed in moderate amounts

Sulfur is part of 3 of the amino acids from which the plant builds protein, and of the oils in canola, mustard and sesame. The plant needs it to turn applied nitrogen into grain protein.

When it is short
Young leaves go pale yellow all over. Nitrogen shortage shows the opposite pattern and starts on the old leaves. Plants are thin and grow slowly, and oilseeds give less oil.
Works with, and against
Sulfur and nitrogen work as a pair: without enough sulfur, extra nitrogen is wasted. Elemental sulfur also makes the soil around each sulfur granule more acidic, and this can release phosphate and zinc that the soil holds near the granule.
In Pakistan’s soils
The Punjab soil testing programme did not test for sulfur, so the Soil Atlas cannot show it. VAN’s soil report does not test for sulfur either. No national figure for soil sulfur has been published.
Zn

Zinc

Micronutrients: 8 needed in grams

Zinc is needed to make the growth hormone that lengthens the stem and the enzymes that build protein. It affects plant height, leaf size and, in rice and wheat, grain set.

When it is short
Young leaves come out small, narrow and yellow between the veins. The stem sections between the leaves (internodes) stay short, so the plant looks bunched. In maize, a white band appears down the young leaf. In rice nurseries, brown spots appear on the older leaves.
Works with, and against
Zinc and phosphorus work against each other, so a heavy phosphate dose makes a zinc shortage worse on a soil already low in zinc. At high pH, the soil binds zinc in the same way as it binds phosphate.
In Pakistan’s soils
The Soil Atlas shows the survey’s median zinc reading for each district; in several districts the median was in the Critical band. A grower can check the district there before deciding on a zinc dose.
B

Boron

Micronutrients: 8 needed in grams

Boron builds the cell wall together with calcium and carries sugar to the flower. It affects pollination, seed set and fruit set. When a cotton boll, a sunflower head or a rice panicle sets badly, boron shortage is often the cause.

When it is short
Growing points die, stems go hollow or cracked, flowers drop without setting, and fruit is misshapen. Cauliflower gets a hollow brown stem, and sugar beet gets a rotten heart.
Works with, and against
Boron and calcium work together at the growing point. The difference between enough boron and too much boron is small, which is why VAN coats boron onto its potash granules rather than relying only on a separate loose dose.
In Pakistan’s soils
In the Punjab soil survey (tested in about 2016 to 2018), 51.7% of samples were below Punjab’s working threshold for boron of 0.5 ppm (parts per million). The Soil Atlas shows each district’s median and its band.
Fe

Iron

Micronutrients: 8 needed in grams

Iron is needed to make chlorophyll and for the enzymes that carry electrons in the leaf. A leaf without iron cannot turn light into sugar.

When it is short
The youngest leaves go yellow between the veins while the veins stay sharply green, and then whole leaves turn white. Old leaves stay green, which distinguishes iron shortage from magnesium shortage.
Works with, and against
Iron and manganese compete for uptake, and at high pH the soil binds both. In Pakistan, iron shortage is usually caused by bicarbonate in irrigation water and lime in the soil, so a soil can hold plenty of iron that the root cannot take up.
In Pakistan’s soils
Iron is tested on VAN’s soil report and shown on the Soil Atlas. In 4 districts, the survey’s iron figures cannot be compared with those of the other 32 districts; the Soil Atlas notes that they suggest a different laboratory method.
Mn

Manganese

Micronutrients: 8 needed in grams

Manganese splits water inside the leaf so that photosynthesis can run, and it helps the plant use nitrogen. It also strengthens the plant’s resistance to fungal disease.

When it is short
Young and middle leaves go yellow between the veins and show grey or brown speckles. In oats and wheat the condition is called grey speck.
Works with, and against
High pH and dry, well-aerated soil both make manganese less available. Too much iron or a heavy dose of lime makes the shortage worse.
In Pakistan’s soils
Manganese is tested on VAN’s soil report and shown on the Soil Atlas.
Cu

Copper

Micronutrients: 8 needed in grams

Copper is needed by the enzymes that build lignin, the woody part of the stem, and for pollen to form. Cereals short of copper produce empty heads.

When it is short
Young leaves twist and wilt at the tip, heads emerge empty or half filled, and stems are weak. Copper shortage is rare in Pakistan.
Works with, and against
Organic matter holds copper tightly, so peaty and heavily manured soils can be short of copper while mineral soils are not.
In Pakistan’s soils
The median copper reading was in the Healthy band in all 32 Punjab districts where the survey figure is comparable. The Soil Atlas marks the other 4 districts as not comparable.
The other 6

The other 6 nutrients: carbon, hydrogen, oxygen, chlorine, molybdenum and nickel

C
Carbon

The crop takes carbon from the air, through the leaf, as carbon dioxide. Every sugar, starch and fibre the crop makes is built from carbon.

H
Hydrogen

The crop takes hydrogen from water, through the root. It is part of every sugar the leaf makes.

O
Oxygen

The crop takes oxygen from air and water. The root needs oxygen to breathe, which is why a crop in a waterlogged field can be short of nutrients even when the soil holds plenty of them.

Cl
Chlorine

Chlorine is needed in small amounts for the working of the leaf pores and for the plant’s water balance. Rain, irrigation water and muriate of potash (MOP) supply it. VAN’s soil report does not test for it.

Mo
Molybdenum

Molybdenum is needed in the smallest amount of all the nutrients, for the enzyme that turns nitrate into protein and for the bacteria that fix nitrogen in pulses. Unlike the other micronutrients, it becomes more available as pH rises. VAN’s soil report does not test for it.

Ni
Nickel

Nickel was the last nutrient to be recognised as essential for plants, in 1987. The plant needs a trace of it for the enzyme that breaks down urea in its tissues. VAN’s soil report does not test for it.